Please note that reservations for Cadillac Mountain are recommended to purchase 90 days in advance. There are also tour guides as well should that interest you.
Lots of companies that provide group or private tours. Here are a couple: https://downeastwindjammer.com/ https://acadianboattours.com/ https://lululobsterboat.com/
Rent bikes to go around town or Acadia National Park: Acadia National Bike Rentals: https://www.acadiabike.com/ Bar Harbor Bikes: http://barharborbike.com/home/